gold foil experiment definition in chemistry

What is the 'Gold Foil Experiment'? The Geiger-Marsden experiments explained

Physicists got their first look at the structure of the atomic nucleus.

J.J. Thomson model of the atom

Gold foil experiments, rutherford model of the atom.

• The real atomic model

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The Geiger-Marsden experiment, also called the gold foil experiment or the α-particle scattering experiments, refers to a series of early-20th-century experiments that gave physicists their first view of the structure of the atomic nucleus and the physics underlying the everyday world. It was first proposed by Nobel Prize -winning physicist Ernest Rutherford.

As familiar as terms like electron, proton and neutron are to us now, in the early 1900s, scientists had very little concept of the fundamental particles that made up atoms . 

In fact, until 1897, scientists believed that atoms had no internal structure and believed that they were an indivisible unit of matter. Even the label "atom" gives this impression, given that it's derived from the Greek word "atomos," meaning "indivisible." 

But that year, University of Cambridge physicist Joseph John Thomson discovered the electron and disproved the concept of the atom being unsplittable, according to Britannica . Thomson found that metals emitted negatively charged particles when illuminated with high-frequency light. 

His discovery of electrons also suggested that there were more elements to atomic structure. That's because matter is usually electrically neutral; so if atoms contain negatively charged particles, they must also contain a source of equivalent positive charge to balance out the negative charge.

By 1904, Thomson had suggested a "plum pudding model" of the atom in which an atom comprises a number of negatively charged electrons in a sphere of uniform positive charge,  distributed like blueberries in a muffin. 

The model had serious shortcomings, however — primarily the mysterious nature of this positively charged sphere. One scientist who was skeptical of this model of atoms was Rutherford, who won the Nobel Prize in chemistry for his 1899 discovery of a form of radioactive decay via α-particles — two protons and two neutrons bound together and identical to a helium -4 nucleus, even if the researchers of the time didn't know this.

Rutherford's Nobel-winning discovery of α particles formed the basis of the gold foil experiment, which cast doubt on the plum pudding model. His experiment would probe atomic structure with high-velocity α-particles emitted by a radioactive source. He initially handed off his investigation to two of his protégés, Ernest Marsden and Hans Geiger, according to Britannica . 

Rutherford reasoned that if Thomson's plum pudding model was correct, then when an α-particle hit a thin foil of gold, the particle should pass through with only the tiniest of deflections. This is because α-particles are 7,000 times more massive than the electrons that presumably made up the interior of the atom.

Marsden and Geiger conducted the experiments primarily at the Physical Laboratories of the University of Manchester in the U.K. between 1908 and 1913. 

The duo used a radioactive source of α-particles facing a thin sheet of gold or platinum surrounded by fluorescent screens that glowed when struck by the deflected particles, thus allowing the scientists to measure the angle of deflection. 

The research team calculated that if Thomson's model was correct, the maximum deflection should occur when the α-particle grazed an atom it encountered and thus experienced the maximum transverse electrostatic force. Even in this case, the plum pudding model predicted a maximum deflection angle of just 0.06 degrees. 

Of course, an α-particle passing through an extremely thin gold foil would still encounter about 1,000 atoms, and thus its deflections would be essentially random. Even with this random scattering, the maximum angle of refraction if Thomson's model was correct would be just over half a degree. The chance of an α-particle being reflected back was just 1 in 10^1,000 (1 followed by a thousand zeroes). 

Yet, when Geiger and Marsden conducted their eponymous experiment, they found that in about 2% of cases, the α-particle underwent large deflections. Even more shocking, around 1 in 10,000 α-particles were reflected directly back from the gold foil.

Rutherford explained just how extraordinary this result was, likening it to firing a 15-inch (38 centimeters) shell (projectile) at a sheet of tissue paper and having it bounce back at you, according to Britannica  

Extraordinary though they were, the results of the Geiger-Marsden experiments did not immediately cause a sensation in the physics community. Initially, the data were unnoticed or even ignored, according to the book "Quantum Physics: An Introduction" by J. Manners.

The results did have a profound effect on Rutherford, however, who in 1910 set about determining a model of atomic structure that would supersede Thomson's plum pudding model, Manners wrote in his book.

The Rutherford model of the atom, put forward in 1911, proposed a nucleus, where the majority of the particle's mass was concentrated, according to Britannica . Surrounding this tiny central core were electrons, and the distance at which they orbited determined the size of the atom. The model suggested that most of the atom was empty space.

When the α-particle approaches within 10^-13 meters of the compact nucleus of Rutherford's atomic model, it experiences a repulsive force around a million times more powerful than it would experience in the plum pudding model. This explains the large-angle scatterings seen in the Geiger-Marsden experiments.

Later Geiger-Marsden experiments were also instrumental; the 1913 tests helped determine the upper limits of the size of an atomic nucleus. These experiments revealed that the angle of scattering of the α-particle was proportional to the square of the charge of the atomic nucleus, or Z, according to the book "Quantum Physics of Matter," published in 2000 and edited by Alan Durrant.  

In 1920, James Chadwick used a similar experimental setup to determine the Z value for a number of metals. The British physicist went on to discover the neutron in 1932, delineating it as a separate particle from the proton, the American Physical Society said . 

What did the Rutherford model get right and wrong?

Yet the Rutherford model shared a critical problem with the earlier plum pudding model of the atom: The orbiting electrons in both models should be continuously emitting electromagnetic energy, which would cause them to lose energy and eventually spiral into the nucleus. In fact, the electrons in Rutherford's model should have lasted less than 10^-5 seconds. 

Another problem presented by Rutherford's model is that it doesn't account for the sizes of atoms. 

Despite these failings, the Rutherford model derived from the Geiger-Marsden experiments would become the inspiration for Niels Bohr 's atomic model of hydrogen , for which he won a Nobel Prize in Physics .

Bohr united Rutherford's atomic model with the quantum theories of Max Planck to determine that electrons in an atom can only take discrete energy values, thereby explaining why they remain stable around a nucleus unless emitting or absorbing a photon, or light particle.

Thus, the work of Rutherford, Geiger  (who later became famous for his invention of a radiation detector)  and Marsden helped to form the foundations of both quantum mechanics and particle physics. 

Rutherford's idea of firing a beam at a target was adapted to particle accelerators during the 20th century. Perhaps the ultimate example of this type of experiment is the Large Hadron Collider near Geneva, which accelerates beams of particles to near light speed and slams them together. 

• See a modern reconstruction of the Geiger-Marsden gold foil experiment conducted by BackstageScience and explained by particle physicist Bruce Kennedy . 
• Find out more about the Bohr model of the atom which would eventually replace the Rutherford atomic model. 
• Rutherford's protege Hans Gieger would eventually become famous for the invention of a radioactive detector, the Gieger counter. SciShow explains how they work .

Thomson's Atomic Model , Lumens Chemistry for Non-Majors,.

Rutherford Model, Britannica, https://www.britannica.com/science/Rutherford-model

Alpha particle, U.S NRC, https://www.nrc.gov/reading-rm/basic-ref/glossary/alpha-particle.html

Manners. J., et al, 'Quantum Physics: An Introduction,' Open University, 2008. 

Durrant, A., et al, 'Quantum Physics of Matter,' Open University, 2008

Ernest Rutherford, Britannica , https://www.britannica.com/biography/Ernest-Rutherford

Niels Bohr, The Nobel Prize, https://www.nobelprize.org/prizes/physics/1922/bohr/facts/

House. J. E., 'Origins of Quantum Theory,' Fundamentals of Quantum Mechanics (Third Edition) , 2018

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Robert Lea is a science journalist in the U.K. who specializes in science, space, physics, astronomy, astrophysics, cosmology, quantum mechanics and technology. Rob's articles have been published in Physics World, New Scientist, Astronomy Magazine, All About Space and ZME Science. He also writes about science communication for Elsevier and the European Journal of Physics. Rob holds a bachelor of science degree in physics and astronomy from the U.K.’s Open University

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What is the model of the atom proposed by Ernest Rutherford?

What is the rutherford gold-foil experiment, what were the results of rutherford's experiment, what did ernest rutherford's atomic model get right and wrong, what was the impact of ernest rutherford's theory.

Rutherford model

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• UC Davis - The Rutherford Scattering Experiment
• Chemistry LibreTexts - Rutherford's Experiment- The Nuclear Model of the Atom

The atom , as described by Ernest Rutherford , has a tiny, massive core called the nucleus . The nucleus has a positive charge. Electrons are particles with a negative charge. Electrons orbit the nucleus. The empty space between the nucleus and the electrons takes up most of the volume of the atom.

A piece of gold foil was hit with alpha particles , which have a positive charge. Most alpha particles went right through. This showed that the gold atoms were mostly empty space. Some particles had their paths bent at large angles. A few even bounced backward. The only way this would happen was if the atom had a small, heavy region of positive charge inside it.

The previous model of the atom, the Thomson atomic model , or the “plum pudding” model, in which negatively charged electrons were like the plums in the atom’s positively charged pudding, was disproved. The Rutherford atomic model relied on classical physics. The Bohr atomic model , relying on quantum mechanics, built upon the Rutherford model to explain the orbits of electrons.

The Rutherford atomic model was correct in that the atom is mostly empty space. Most of the mass is in the nucleus, and the nucleus is positively charged. Far from the nucleus are the negatively charged electrons. But the Rutherford atomic model used classical physics and not quantum mechanics. This meant that an electron circling the nucleus would give off electromagnetic radiation . The electron would lose energy and fall into the nucleus. In the Bohr model, which used quantum theory, the electrons exist only in specific orbits and can move between these orbits.​

The gold-foil experiment showed that the atom consists of a small, massive, positively charged nucleus with the negatively charged electrons being at a great distance from the centre. Niels Bohr built upon Rutherford’s model to make his own. In Bohr’s model the orbits of the electrons were explained by quantum mechanics.

Rutherford model , description of the structure of atoms proposed (1911) by the New Zealand-born physicist Ernest Rutherford . The model described the atom as a tiny, dense, positively charged core called a nucleus, in which nearly all the mass is concentrated, around which the light, negative constituents , called electrons , circulate at some distance, much like planets revolving around the Sun .

The nucleus was postulated as small and dense to account for the scattering of alpha particles from thin gold foil, as observed in a series of experiments performed by undergraduate Ernest Marsden under the direction of Rutherford and German physicist Hans Geiger in 1909. A radioactive source emitting alpha particles (i.e., positively charged particles, identical to the helium atom nucleus and 7,000 times more massive than electrons) was enclosed within a protective lead shield. The radiation was focused into a narrow beam after passing through a slit in a lead screen. A thin section of gold foil was placed in front of the slit, and a screen coated with zinc sulfide to render it fluorescent served as a counter to detect alpha particles. As each alpha particle struck the fluorescent screen , it produced a burst of light called a scintillation, which was visible through a viewing microscope attached to the back of the screen. The screen itself was movable, allowing Rutherford and his associates to determine whether or not any alpha particles were being deflected by the gold foil.

Most alpha particles passed straight through the gold foil, which implied that atoms are mostly composed of open space. Some alpha particles were deflected slightly, suggesting interactions with other positively charged particles within the atom. Still other alpha particles were scattered at large angles, while a very few even bounced back toward the source. (Rutherford famously said later, “It was almost as incredible as if you fired a 15-inch shell at a piece of tissue paper and it came back and hit you.”) Only a positively charged and relatively heavy target particle, such as the proposed nucleus, could account for such strong repulsion. The negative electrons that balanced electrically the positive nuclear charge were regarded as traveling in circular orbits about the nucleus. The electrostatic force of attraction between electrons and nucleus was likened to the gravitational force of attraction between the revolving planets and the Sun. Most of this planetary atom was open space and offered no resistance to the passage of the alpha particles.

The Rutherford model supplanted the “plum-pudding” atomic model of English physicist Sir J.J. Thomson , in which the electrons were embedded in a positively charged atom like plums in a pudding. Based wholly on classical physics , the Rutherford model itself was superseded in a few years by the Bohr atomic model , which incorporated some early quantum theory . See also atomic model .

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Who did the Gold Foil Experiment?

The gold foil experiment was a pathbreaking work conducted by scientists Hans Geiger and Ernest Marsden under the supervision of Nobel laureate physicist Ernest Rutherford that led to the discovery of the proper structure of an atom . Known as the Geiger-Marsden experiment, it was performed at the Physical Laboratories of the University of Manchester between 1908 and 1913.

The prevalent atomic theory at the time of the research was the plum pudding model that was developed by Lord Kelvin and further improved by J.J. Thomson. According to the theory, an atom was a positively charged sphere with the electrons embedded in it like plums in a Christmas pudding.

With neutrons and protons yet to be discovered, the theory was derived following the classical Newtonian Physics. However, in the absence of experimental proof, this approach lacked proper acceptance by the scientific community.

What is the Gold Foil Experiment?

Description.

The method used by scientists included the following experimental steps and procedure. They bombarded a thin gold foil of thickness approximately 8.6 x 10 -6 cm with a beam of alpha particles in a vacuum. Alpha particles are positively charged particles with a mass of about four times that of a hydrogen atom and are found in radioactive natural substances. They used gold since it is highly malleable, producing sheets that can be only a few atoms thick, thereby ensuring smooth passage of the alpha particles. A circular screen coated with zinc sulfide surrounded the foil. Since the positively charged alpha particles possess mass and move very fast, it was hypothesized that they would penetrate the thin gold foil and land themselves on the screen, producing fluorescence in the part they struck.

Like the plum pudding model, since the positive charge of atoms was evenly distributed and too small as compared to that of the alpha particles, the deflection of the particulate matter was predicted to be less than a small fraction of a degree.

Observation

Though most of the alpha particles behaved as expected, there was a noticeable fraction of particles that got scattered by angles greater than 90 degrees. There were about 1 in every 2000 particles that got scattered by a full 180 degree, i.e., they retraced their path after hitting the gold foil.

Simulation of Rutherford’s Gold Foil Experiment Courtesy: University of Colorado Boulder

The unexpected outcome could have only one explanation – a highly concentrated positive charge at the center of an atom that caused an electrostatic repulsion of the particles strong enough to bounce them back to their source. The particles that got deflected by huge angles passed close to the said concentrated mass. Most of the particles moved undeviated as there was no obstruction to their path, proving that the majority of an atom is empty.

In addition to the above, Rutherford concluded that since the central core could deflect the dense alpha particles, it shows that almost the entire mass of the atom is concentrated there. Rutherford named it the “nucleus” after experimenting with various gases. He also used materials other than gold for the foil, though the gold foil version gained the most popularity.

He further went on to reject the plum pudding model and developed a new atomic structure called the planetary model. In this model, a vastly empty atom holds a tiny nucleus at the center surrounded by a cloud of electrons. As a result of his gold foil experiment, Rutherford’s atomic theory holds good even today.

Rutherford’s Atomic Model

Rutherford’s Gold Foil Experiment Animation

• Rutherford demonstrated his experiment on bombarding thin gold foil with alpha particles contributed immensely to the atomic theory by proposing his nuclear atomic model.
• The nuclear model of the atom consists of a small and dense positively charged interior surrounded by a cloud of electrons.
• The significance and purpose of the gold foil experiment are still prevalent today. The discovery of the nucleus paved the way for further research, unraveling a list of unknown fundamental particles.
• Chemed.chem.purdue.edu
• Chem.libretexts.org
• Large.stanford.edu
• Radioa ctivity.eu.com

Article was last reviewed on Friday, February 3, 2023

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Super very much helpful to me,clear explanation about every act done by our Rutherford that is under different sub headings ,which is very much clear to ,to study .very much thanks to the science facts.com.thank u so much.

Good explanation,very helpful ,thank u ,so much

very clear and helpful, perfect for my science project!

Thank you for sharing the interactive program on the effects of the type of atom on the experiment! Looking forward to sharing this with my ninth graders!

Rutherford spearheaded with a team of scientist in his experiment of gold foil to capture the particles of the year 1911. It’s the beginning of explaining particles that float and are compacted . Rutherford discovered this atom through countless experiments which was the revolutionary discovery of the atomic nuclear . Rutherford name the atom as a positive charge and the the center is the nucleus.

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Video transcript

Rutherford Atomic Model

Definition of the rutherford model.

The Rutherford atomic model has 2 main parts: the nucleus, and the atom’s remaining space, occupied by electrons.

According to the model, the nucleus is a very small portion of the atom’s volume. It occupies a small space in the very center of the atom. Protons and neutrons make up the nucleus and define the atom’s chemical properties.

Rutherford also claimed in his model that electrons revolved around the nucleus in set orbits, like planets revolving around the Sun. This part of the theory was inaccurate, as explained in the last section.

Rutherford’s Gold Foil Experiment

The Rutherford gold foil experiment , also known as the scattering experiment, led to the creation of the model and explained the parts of the atom. In 1909, graduate student Ernest Marsden (under Ernest Rutherford’s supervision) fired alpha particles at a gold foil piece. Most of the particles passed directly through the foil, meaning that a majority of the space in each atom was unoccupied. However, a few particles were deflected, and some even backward. This must have been caused by tiny pockets of positive charge in the foil repelling the alpha particles back. Their discovery led to the creation of Rutherford’s model, in which the dense, positively-charged nucleus occupies a very small area in the center of each atom.

Shortcomings of the Rutherford Model

While common models today are based on the Rutherford atomic theory, it does not paint the complete picture:

• The model is missing parts and does not account for the location or distribution of electrons.
• Rutherford proposed that electrons orbit around the nucleus in set paths, but according to Maxwell’s theory , this is not possible because the atom would not be stable. Electromagnetic radiation from the electrons in orbit would cause the atom to collapse into the nucleus in 10 -8 seconds.
• Electrons increase and decrease energy levels randomly due to the acceleration and are not always in a standard circular orbit. They give off electromagnetic radiation due to the circular motion of orbiting; thus they must have some initial energy by the law of conservation of energy. The Rutherford atomic model does not account for the initial energy and subsequent energy level changes.

Further Reading

• Dalton’s Atomic Theory
• Bohr Atomic Model
• The Structure of an Atom

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About Rutherford's Gold Foil Experiment

Five Types of Atomic Models

Ernest Rutherford, originally from New Zealand, is credited as being the father of nuclear physics for his discoveries in atomic structure, even though Hantaro Nagaoka, a physicist from the Imperial University of Tokyo, first proposed the theory of the nucleus as it is known today. Rutherford's "gold foil experiment" led to the discovery that most of an atom's mass is located in a dense region now called the nucleus. Prior to the groundbreaking gold foil experiment, Rutherford was granted the Nobel Prize for other key contributions in the field of chemistry.

The popular theory of atomic structure at the time of Rutherford's experiment was the "plum pudding model." This model was developed in 1904 by J.J. Thompson, the scientist who discovered the electron. This theory held that the negatively charged electrons in an atom were floating in a sea of positive charge--the electrons being akin to plums in a bowl of pudding. Although Dr. Nagaoka had published his competing theory that electrons orbit a positive nucleus, akin to the way the planet Saturn is orbited by its rings, in 1904, the plum pudding model was the prevailing theory on the structure of the atom until it was disproved by Ernest Rutherford in 1911.

The gold foil experiment was conducted under the supervision of Rutherford at the University of Manchester in 1909 by scientist Hans Geiger (whose work eventually led to the development of the Geiger counter) and undergraduate student Ernest Marsden. Rutherford, chair of the Manchester physics department at the time of the experiment, is given primary credit for the experiment, as the theories that resulted are primarily his work. Rutherford's gold foil experiment is also sometimes referred to as the Geiger-Marsden experiment.

The gold foil experiment consisted of a series of tests in which a positively charged helium particle was shot at a very thin layer of gold foil. The expected result was that the positive particles would be moved just a few degrees from their path as they passed through the sea of positive charge proposed in the plum pudding model. The result, however, was that the positive particles were repelled off of the gold foil by nearly 180 degrees in a very small region of the atom, while most of the remaining particles were not deflected at all but rather passed right through the atom.

Significance

The data generated from the gold foil experiment demonstrated that the plum pudding model of the atom was incorrect. The way in which the positive particles bounced off the thin foil indicated that the majority of the mass of an atom was concentrated in one small region. Because the majority of the positive particles continued on their original path unmoved, Rutherford correctly deducted that most of the remainder of the atom was empty space. Rutherford termed his discovery "the central charge," a region later named the nucleus.

Rutherford's discovery of the nucleus and proposed atomic structure was later refined by physicist Niels Bohr in 1913. Bohr's model of the atom, also referred to as the Rutherford Bohr model, is the basic atomic model used today. Rutherford's description of the atom set the foundation for all future atomic models and the development of nuclear physics.

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Gold Foil Experiment — Overview & Importance - Expii

Gold Foil Experiment

Conducted by Ernest Rutherford, this experiment involved shooting alpha particles at thin gold foil. Most passed through but some were deflected, leading to the conclusion that most of an atom's mass is concentrated in its nucleus.

Related terms

Alpha Particle : A positively charged particle consisting of two protons and two neutrons.

Nucleus : The small, dense region at the center of an atom where protons and neutrons are located.

Atomic Mass : The mass of an atom, most of which is concentrated in the nucleus.

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Rutherford's gold foil experiment was a major milestone in the determination of the size and proportions of the different constituents of the atom. It was successful in determining that the majority of the mass of an atom lies within the nucleus, just as the majority of the mass of a planetary system lies within the stellar system of that planetary system.

Rutherford measured the amount and frequency of deflection of alpha particles as they were shot through a very thin gold foil. Ruthford, How I did the experiment This helped to determine that the nucleus of the atom is contained to a very small portion of the atom, at it's center. The deflection of the alpha particles was incorrectly reasoned to be due to the like charges of the alpha particle and the nucleus of the gold atoms. This incorrect reasoning was no fault of Rutherford, however, as by that time in history, the concept of electric charges within the atom had already been incorrectly established as the reason for attraction and repulsion of the atomic constituents. So, it was obvious that the alpha particles were being deflected by the nucleus, but the reason for the deflection was misconstrued, no fault of Rutherford's.

In the AAM, there is no concept of electric charge. All matter is attracted to other matter, by the same force which is responsible for gravity. Thus, the alpha particles which pass through the gold foil and pass close enough to the nucleus of a gold atom are attracted to the nucleus, which causes the alpha particle trajectory to bend towards the nucleus, not away from it, as shown in figure 2 below.

The experimental results of either case above will be very much the same. There would be small differences, however, which may be able to determine which case is actually correct. In the conventional explanation, as shown in Figure 1 above, it's possible for an alpha particle to be deflected 180%, and return strait back to the source in which it came. In the second case, this would not be possible, since the alpha particle would collide with the gold nucleus.

Modification of the gold foil experiment may also help to determine which case is valid. If the alpha particles were to be show slowly in the gold foil, the patterns of deflections may be calculated to be different for each case, since the repulsive force in the first case would cause a different amount of deflection than the attractive forces in the second case. So, this experiment would be very good to revive, with this new concept in mind, and with keeping an open mind to the possibility that it is an attractive force causing the deflections of the alpha particles.

For the discussion on why the alpha particles are attracted to the nucleus, please see Gravity and Electric Charge .

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What is a Gold foil experiment?

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